NaOH (Sodium Hydroxide), also known as caustic soda, is one of the strong alkaline compounds and is widely used in many industries. This chemical exists in two main forms: liquid and solid (caustic soda flakes, pellets, blocks). To better understand the applications and effectiveness of NaOH, we need to learn more about its typical physical and chemical properties.
Physical properties of NaOH, caustic soda flakes
1. Physical state
- Liquid form: Liquid NaOH is usually colorless or opaque white, depending on the concentration. Common concentrations of liquid NaOH include: 20%, 32%, 45%, 50%.
- Solid form: High concentration (99%) NaOH flakes or pellets are usually opaque white, have regular shape, and are easy to store and transport.
2. Density and melting point
- Proportion:
- Liquid NaOH solution has a specific gravity ranging from 1,2 - 1,5 g/cc depending on the content.
- Solid NaOH (caustic soda flakes) has a high specific gravity, up to 2,13 g / cm³ at 20°C.
- Melting temperature:
- Solid NaOH has a melting point of about 318°C and the boiling point is up to 1.388°C, indicating the high thermal stability of this chemical.
3. Solubility and heat generation properties
- NaOH easily dissolves completely in water, forming a strong alkaline solution.
- The process of dissolving NaOH in water generates a lot of heat (ΔH₀: -44,5 kJ/mol), which can cause burns if not careful in preparation.
4. Hydration state
- In solution, NaOH can form monohydrate at about temperature 12,3 ° C - 61,8 ° C with the melting point of the hydrate form being 65,1°C.

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Chemical properties of NaOH, caustic soda flakes
1. Strong alkalinity
NaOH is a strong base, capable of neutralizing acids, reacting strongly with many chemical compounds, creating important products in industry.
2. Typical chemical reactions
- Reaction with acids: Form salt and water.
- Equation: NaOH + HCl → NaCl + H₂O.
- Reaction with acid oxides:
- For example: 2 NaOH + CO₂ → Na₂CO₃ + H₂O.
- Reaction with salt: Form new salts and new bases.
- For example: 2 NaOH + CuCl₂ → 2 NaCl + Cu(OH)₂.
- Reaction with strong metals: Create new bases and new metals.
- For example: NaOH + K → KOH + Na.
3. Corrosion
NaOH is a highly corrosive chemical, especially to metals (aluminum, zinc), non-alkali resistant plastics, and organic materials. This requires the use of alkali-resistant containers and strict protective measures when working with this chemical.

Comparison of liquid NaOH and caustic soda flakes
| Characteristic | Liquid NaOH | NaOH caustic soda flakes |
|---|---|---|
| Physical state | White, opaque liquid solution | Solid, scaly, opaque white |
| Content | 20%, 32%, 45%, 50% | 99% |
| Advantages | Easy to mix, use directly | Easy to store, transport, pure |
| Main application | Increase pH, water treatment, sanitation | Production of soap, paper, chemicals |
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Applications of NaOH, caustic soda flakes related to physical and chemical properties
1. Water treatment
- Increase pH: NaOH is used to adjust pH in water treatment, remove impurities and bacteria.
- Cleaning and disinfection: Due to its strong alkalinity, caustic soda flakes are used to produce Javen water (Sodium Hypochlorite) to disinfect swimming pool water.
2. Paper and rayon industry
- NaOH dissolves lignin in wood pulp, making the fiber separation process in paper production more efficient.
- In the rayon industry, NaOH decomposes cellulose and lignin, creating raw materials for the spinning process.
3. Food industry
- Refining oil and fat: NaOH removes fatty acids in grease, helps refine vegetable and animal oils, ensuring food hygiene and safety.
- Cleaning equipment: Clean and sanitize bottles and food preparation equipment.
4. Chemical industry
- Soap and detergent production: NaOH reacts with fats in oils and grease to create soap.
- Other chemical production: It is the basic raw material for the production of Sodium Silicate, PAC, and many other industrial chemicals.
5. Textile industry
- Fabric treatment: NaOH removes pectin and waxes from fabrics, making them shinier and increasing color absorption.
NaOH, whether in liquid or solid form, is an important basic chemical with many outstanding properties, suitable for many industrial applications. With its special physical and chemical properties, NaOH is always the preferred choice for manufacturing industries that require high efficiency, cost savings and environmental safety. If you need more information or support about NaOH products, please contact Loc Thien Investment and Development Company Limited to receive dedicated advice and the best solution!



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